1,3-Dibromo-5,5-dimethylhydantoin (DBH) as a cheap and efficient catalyst for the synthesis of polyhydroquinolines and 12-aryl-8,9,10,12-tetrahydro [a] xanthene-11-ones

نویسندگان

  • Farhad Shirini Department of Chemistry, College of Science, University of Guilan, Rasht, zip code 41335, I.R. Iran.
  • Gholam Hossein Imanzadeh Department of Chemistry, College of Science, University of Mohaghegh Ardabili, Ardabil, Iran.
  • Masoumeh Abedini Department of Chemistry, College of Science, University of Guilan, Rasht, zip code 41335, I.R. Iran.
  • Parisa Ghods Ghasemabadi Department of Chemistry, College of Science, University of Guilan, Rasht, zip code 41335, I.R. Iran. Department of Chemistry, College of Science, University of Mohaghegh Ardabili, Ardabil, Iran.
چکیده مقاله:

1,3-Dibromo-5,5-dimethylhydantoin (DBH), as a cheap and commercially available reagent, is efficiently able to catalyze the synthesis of polyhydroquinoline derivatives and 12-aryl-8,9,10,12-tetrahydro[a] xanthene-11-ones via one-pot multi-component reactions. This novel synthetic method has the advantages of low cost and availability of the catalyst, short reaction times, high to excellent yields, simple and easy work-up and purification of the products compared to the conventional methods reported in the literature.

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منابع مشابه

1,3-dibromo-5,5-dimethylhydantoin (dbh) as a cheap and efficient catalyst for the synthesis of polyhydroquinolines and 12-aryl-8,9,10,12-tetrahydro [a] xanthene-11-ones

1,3-dibromo-5,5-dimethylhydantoin (dbh), as a cheap and commercially available reagent, is efficiently able to catalyze the synthesis of polyhydroquinoline derivatives and 12-aryl-8,9,10,12-tetrahydro[a] xanthene-11-ones via one-pot multi-component reactions. this novel synthetic method has the advantages of low cost and availability of the catalyst, short reaction times, high to excellent yiel...

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Triethylamine-bonded sulfonic acid {[Et3N-SO3H]Cl} as an efficient and homogeneous catalyst for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones

Brønsted acidic ionic liquid triethylamine-bonded sulfonic acid {[Et3N-SO3H]Cl} efficiently catalyzes the one-pot multi-component condensation of 2-naphthol with arylaldehydes and dimedone (5,5-dimethylcyclohexane-1,3-dione) under solvent-free conditions to afford 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones in high yields and relatively short reaction times.

متن کامل

Triethylamine-bonded sulfonic acid {[Et3N-SO3H]Cl} as an efficient and homogeneous catalyst for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones

Brønsted acidic ionic liquid triethylamine-bonded sulfonic acid {[Et3N-SO3H]Cl} efficiently catalyzes the one-pot multi-component condensation of 2-naphthol with arylaldehydes and dimedone (5,5-dimethylcyclohexane-1,3-dione) under solvent-free conditions to afford 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones in high yields and relatively short reaction times.

متن کامل

triethylamine-bonded sulfonic acid {[et3n-so3h]cl} as an efficient and homogeneous catalyst for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones

brønsted acidic ionic liquid triethylamine-bonded sulfonic acid {[et3n-so3h]cl} efficiently catalyzes the one-pot multi-component condensation of 2-naphthol with arylaldehydes and dimedone (5,5-dimethylcyclohexane-1,3-dione) under solvent-free conditions to afford 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-ones in high yields and relatively short reaction times.

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عنوان ژورنال

دوره 3  شماره 2

صفحات  57- 65

تاریخ انتشار 2013-06-01

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